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Beilstein J. Org. Chem. 2018, 14, 1537–1545, doi:10.3762/bjoc.14.130
Graphical Abstract
Scheme 1: Cycloaddition reaction of in situ generated benzynes resulting in the sterically more hindered addu...
Scheme 2: Recently developed cobalt-catalyzed C–H cyanation [30].
Figure 1: Calculated free-energy profile for the cobalt-catalyzed C–H cyanation of 2-phenylpyridine (1a) [in ...
Figure 2: Calculated structures, selected bond lengths (in Å), and imaginary frequencies for representative i...
Scheme 3: Kinetic profile of the cobalt-catalyzed C–H cyanation with differently substituted cyanating agents ...
Figure 3: Noncovalent interaction (NCI) analysis for selected intermediates and transition states. The gradie...
Figure 4: Projected dispersion interaction density (DID) plots for selected intermediates and transition stat...